Tubos de ensaio
Main-group and
Organometallic chemistry
helical.jpg

[54] Chem. Sci. 2021, Accepted.

One- and Two-Electron Reduction of Triarylborane-Based Helical Donor-Acceptor Compounds

X. Jia, J. Nitsch, Z. Wu, A. Friedrich, J. Krebs, I. Krumennacher, F. Fantuzzi, H. Braunschweig, M. Moos, C. Lambert, B. Engels, T. Marder*

DOI: 10.1039/D1SC02409D

berad.jpg

[53] Angew. Chem. Int. Ed. 2021, Accepted.

A Neutral Beryllium(I) Radical

C. Czernetzki, M. Arrowsmith, F. Fantuzzi, A. Gärtner, I. Krummenacher, F. Schorr, T. Tröster, H. Braunschweig*

DOI: soon

DOI (German version): soon

beryllole.jpg

[52] Angew. Chem. Int. Ed. 2021, 60, 3812–3819.

Isolation and Reactivity of an Antiaromatic s-Block Metal Compound

D. K. Roy, T. Tröster, F. Fantuzzi, R. D. Dewhurst, C. Lenczyk, K. Radacki, C. Pranckevicius, B. Engels*, H. Braunschweig*

Highlighted in Chemistry World

DOI: 10.1002/anie.202014557

DOI (German version): 10.1002/ange.202014557

pt-frame2.jpg

[51] Angew. Chem. Int. Ed. 2021, Accepted.

Platinum-Templated Coupling of B=N Units: Synthesis of BNBN Analogues of 1,3-Dienes and a Butatriene

C. Brunecker, M. Arrowsmith, F. Fantuzzi, H. Braunschweig*

DOI: 10.1002/anie.202106161

DOI (German version): 10.1002/ange.202106161

b2p2.jpg

[50] Angew. Chem. Int. Ed. 2021, 60, 13661–13665.

Isolation of Neutral, Mono-, and Dicationic B2P2 Rings by Diphosphorus Addition to a Boron–Boron Triple Bond

T. Brückner, F. Fantuzzi, T. E. Stennett, I. Krummenacher, R. D. Dewhurst, B. Engels, H. Braunschweig*

DOI: 10.1002/anie.202102218

DOI (German version): 10.1002/ange.202102218

h2bpco.jpg

[49] Angew. Chem. Int. Ed. 2021, 60, 13666–13670.

Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry

S. Hagspiel, F. Fantuzzi, R. D. Dewhurst, A. Gärtner, F. Lindl, A. Lamprecht, H. Braunschweig*

DOI: 10.1002/anie.202103521

DOI (German version): 10.1002/ange.202103521

bncs.jpg

[48] Angew. Chem. Int. Ed. 2021, 60, 6446–6450.

Highly Colored Boron-Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates

S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, A. Hermann, T. Brückner, H. Braunschweig*

DOI: 10.1002/anie.202015508

DOI (German Version): 10.1002/ange.202015508

bco.jpg

[47] Angew. Chem. Int. Ed. 2021, 2963–2968.

Reduction and Rearrangement of a Boron(I) Carbonyl Complex

M. Rang, F. Fantuzzi, M. Arrowsmith, I. Krummenacher, E. Beck, R. Witte, A. Matler, A. Rempel, T. Bischof, K. Radacki, B. Engels, H. Braunschweig*

DOI: 10.1002/anie.202014167

DOI (German Version): 10.1002/ange.202014167

cyano-isothio.jpg

[46] Chem. Sci. 2021, Accepted.

Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity

S. Hagspiel, E. Dren, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, M. Härterich, I. Krummenacher,  H. Braunschweig*

DOI: soon

alkynyl.jpg

[45] Chem. Commun. 2021, 57, 2645–2648.

Dialkynyldiboranes(4) and the selectable reactivity of their C–H, C≡C and B–B bonds

F. Schorr, F. Fantuzzi, R. D. Dewhurst, H. Braunschweig*

DOI: 10.1039/D1CC00265A

bridged.jpg

[44] Chem. Eur. J. 2021, 27, 5160–5170.

Twisting versus Delocalization in CAAC- and NHC-Stabilized Boron-Based Biradicals: The Roles of Sterics and Electronics

P. Schmid, F. Fantuzzi, J. Klopf, N. B. Schröder, R. D. Dewhurst, H. Braunschweig, V. Engel, B. Engels*

Highlighted as Front Cover

Highlighted as Cover Profile

DOI: 10.1002/chem.202004619

mn2.jpg

[43] Chem. Eur. J. 2021, Accepted.

Taming the Antiferromagnetic Beast: Computational Design of Ultrashort Mn−Mn Bonds Stabilized by N-Heterocyclic Carbenes

M. A. S. Francisco,† F. Fantuzzi*, T. M. Cardozo, P. M. Esteves, B. Engels, R. R. Oliveira* (†: contributed equally)

DOI: Soon

nb2.jpg

[42] Dalton Trans. 2021, 50, 840–849.

Splitting of Multiple Hydrogen Molecules by Bioinspired Diniobium Metal Complexes: A DFT Study

F. Fantuzzi, M. A. C. Nascimento*, B. Ginovska, R. M. Bullock, S. Raugei*

Highlighted as Front Cover

Highlighted in Dalton Transactions HOT Articles
DOI: 10.1039/D0DT03411H

rhodium.jpg

[41] J. Org. Chem. 2021, 86, 264–278.

Rhodium(III)-Catalyzed C–H/N–H Alkyne Annulation of Non-Symmetric 2-Aryl-(Benz)Imidazole Derivatives: Photophysical and Mechanistic Insights

G. Dias, E. Paz, J. Kadooka, A. Sabino, L. Cury, K. Torikai, C. Simone, F. Fantuzzi, E. N. da Silva Jr.*

DOI: 10.1021/acs.joc.0c02054

lif.jpg

[40] J. Appl. Phys. 2021, 129, 205102.

Ab initio study of structural and electronic properties of lithium fluoride nanotubes

R. R. Oliveira*, F. Fantuzzi*, M. A. C. Nascimento*

DOI: 10.1063/5.0047243

dba.jpg

[39] Angew. Chem. Int. Ed. 2020, 59, 19338–19343.

cAAC-Stabilized 9,10-diboraanthracenes – acenes with open-shell singlet biradical ground states

C. Saalfrank, F. Fantuzzi, T. Kupfer, B. Ritschel, A. Matler, K. Hammond, I. Krummenacher, R. Bertermann, R. Wirthensohn, M. Finze, P. Schmid, V. Engel, B. Engels, H. Braunschweig*

Very Important Paper

DOI: 10.1002/anie.202008206

DOI (German version): 10.1002/ange.202008206

vinyldib.jpg

[38] Angew. Chem. Int. Ed. 2020, 59, 15717–15725.

Oxidation, Coordination and Nickel-Mediated Deconstruction of a Highly Electron-Rich Diboron Analogue of 1,3,5-Hexatriene

A. Herrmann†, F. Fantuzzi†, M. Arrowsmith, T. Zorn, I. Krummenacher, B. Ritschel, K. Radacki, B. Engels, H. Braunschweig*  (†: contributed equally)

DOI: 10.1002/anie.202006131

DOI (German version): 10.1002/ange.202006131

azides.jpg

[37] Angew. Chem. Int. Ed. 2020, 59, 15480–15486.

Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes

T. Thiess, G. Bélanger-Chabot†, F. Fantuzzi, M. Michel, M. Ernst, B. Engels, H. Braunschweig* (†: contributted equally)

DOI: 10.1002/anie.202003050

DOI (German version): 10.1002/ange.202003050

toc_stephan.gif

[36] Chem. Sci. 2020, 11, 551–555.

Reduction of a Dihydroboryl Cation to a Boryl Anion and its Air-Stable, Neutral Hydroboryl Radical through Hydrogen Shuttling

S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Hermann, V. Paprocki, R. Drescher, I. Krummenacher, H. Braunschweig*
 

DOI: 10.1039/C9SC05026D

rhazaborete.jpg

[35] Chem. Sci. 2020, 11, 9134–9140.

Diverse Ring-Opening Reactions of Rhodium η4-Azaborete Complexes

M. Heß, T. E. Stennett, F. Fantuzzi, R. Bertermann, M. Schock, M. Schäfer, T. Thiess, H. Braunschweig*

DOI: 10.1039/D0SC02283G

boratafulv.jpg

[34] Chem. Commun. 2020, 56, 14809–14812.

Tuneable reduction of cymantrenylboranes to diborenes or borylene-derived boratafulvenes

U. Schmidt, F. Fantuzzi, M. Arrowsmith, A. Hermann, D. Prieschl, A. Rempel, B. Engels, H. Braunschweig*

DOI: 10.1039/D0CC06398C

ruthenium.jpg

[33] Chem. Eur. J. 2020, 26, 10981–10986.

Ruthenium(II)-Catalyzed Double Annulation of Quinones: Step-Economical Access to Valuable Bioactive Compounds

E. N. da Silva Jr.*, R. L. Carvalho, R. G. Almeida, L. G. Rosa, F. Fantuzzi, T. Rogge, P. M. S. Costa, C. O. Pessoa, C. Jacob, L. Ackermann*

Highlighted in Hot Topic: C-H Activation

Special Issue: 8th EuChemS Chemistry Congress

DOI: 10.1002/chem.202001434

ptaframe.jpg

[32] Chem. Eur. J. 2020, 26, 8518–8523.

Boranediyl- and Diboran(4)-1,2-diyl-bridged Platinum A-Frame Complexes

C. Brunecker, J. H. Müssig, M. Arrowsmith, F. Fantuzzi, A. Stoy, J. Böhnke, A. Hofmann, R. Bertermann, B. Engels, H. Braunschweig*

DOI: 10.1002/chem.202001168

wn2.jpg

[31] Chem. Eur. J. 2020, 26, 16019–16027.

Functionalization of N2 via Formal 1,3-Haloboration of a Tungsten(0) σ-Dinitrogen Complex

A. Rempel, S. K. Mellerup. F. Fantuzzi, A. Herzog, A. Deißenberger, R. Bertermann, B. Engels, H. Braunschweig*

DOI: 10.1002/chem.202002678

2019_Soren.jpg

[30] J. Am. Chem. Soc. 2019, 141, 1695416960.

Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions

S. Mellerup, Y. Cui, F. Fantuzzi, P. Schmid, J. Goettel, G. Bélanger-Chabot, M. Arrowsmith, I. Krummenacher, Q. Ye, V. Engel, B. Engels, H. Braunschweig*

DOI: 10.1021/jacs.9b09128

2019_conor.jpg

[29] Angew. Chem. Int. Ed. 2019, 58, 12893–12897.

Bond‐Strengthening Backdonation in Aminoborylene‐Stabilized Aminoborylenes: At the Intersection of Borylenes and Diborenes

C. Pranckevicius, C. Herok, F. Fantuzzi, B. Engels, H. Braunschweig*

Hot Paper

Special Issue: Science Forum 2019

DOI: 10.1002/anie.201906671

DOI (German version): 10.1002/ange.201906671

2019_valerie

[28] Chem. Commun. 2019, 55, 9677–9680.

Selective Mono- and Dimetallation of a Group 3 Sandwich Complex

A. J. Martínez-Martínez, A. R. Kennedy, V. Paprocki, F. Fantuzzi, R. D. Dewhurst, C. T. O'Hara, H. Braunschweig*, R. E. Mulvey*

DOI: 10.1039/C9CC03825F

2019_LiF.jpg

[27] Chem. Eur. J. 2019, 25, 5269–5279.

Mechanistic Insights into the Formation of Lithium Fluoride Nanotubes

F. Fantuzzi, R. R. Oliveira, A. Henkes, J. Rubayo-Soneira, M. A. C. Nascimento*

DOI: 10.1002/chem.201805991

2019_Dibnano.jpg

[26] Inorg. Chem. 2018,  57, 3931–3940.

Diboryne Nanostructures Stabilized by Multitopic N-Heterocyclic Carbenes: A Computational Study

F. Fantuzzi, C. B. Coutinho, R. R. Oliveira, M. A. C. Nascimento*

DOI: 10.1021/acs.inorgchem.8b00089

78779489-2.jpg

[25] Chem. Eur. J. 2015, 21, 7814–7819.

Prediction of Boron-Boron Triple-Bond Polymers Stabilized by Janus-Type bis(N-Heterocyclic) Carbenes

F. Fantuzzi, M. A. C. Nascimento*

DOI: 10.1002/chem.201500241

78779489-2.jpg

[24] Synlett 2014, 25, 1043–1044.

Mercury(II) Chloride

F. Fantuzzi*

DOI: 10.1055/s-0033-1340958