Tubos de ensaio
Main-group and
Organometallic chemistry
dpnicta.jpg

[60] Angew. Chem. Int. Ed. 2021, Accepted.

Cyclo-Dipnictadialanes

S. Nees†, F. Fantuzzi†, T. Wellnitz, M. Fischer, J.-E. Siewert, J. T. Goettel, A. Hofmann, M. Härterich, H. Braunschweig*, C. Hering-Junghans* 
(†: contributed equally) 

DOI: 10.1002/anie.202111121

DOI (German Version): 10.1002/ange.202111121

bismuth.jpg

[59] Angew. Chem. Int. Ed. 2021, Accepted.

The Dimethylbismuth Cation: Entry into Dative Bi–Bi Bonding and Unconventional Methyl Exchange

J. Ramler, F. Fantuzzi, F. Geist, A. Hanft, H. Braunschweig, B. Engels, C. Lichtenberg*

Hot Paper

DOI: 10.1002/anie.202109545

DOI (German Version): 10.1002/ange.202109545

bbolig.jpg

[58] Chem. Eur. J. 2021, Accepted.

Controlled Synthesis of Oligomers Containing Main-Chain B(sp2)-B(sp2) Bonds

F. Schorr, N. Schopper, N. Riensch, F. Fantuzzi, M. Neder, R. Dewhurst, T. Thiess, T. Brückner, K. Hammond, H. Helten, M. Finze, H. Braunschweig*

DOI: 10.1002/chem.202102721

naphth.jpg

[57] Chem. Eur. J. 2021, Accepted.

Diphosphino-Functionalized 1,8-Naphthyridines: a Multifaceted Ligand Platform for Boranes and Diboranes

J. Cui, M. Dietz, M. Härterich, F. Fantuzzi, W. Lu, R. Dewhurst, H. Braunschweig*

DOI: 10.1002/chem.202102721

berad.jpg

[56] Angew. Chem. Int. Ed. 2021, 60, 20776-20780.

A Neutral Beryllium(I) Radical

C. Czernetzki, M. Arrowsmith, F. Fantuzzi, A. Gärtner, I. Krummenacher, F. Schorr, T. Tröster, H. Braunschweig*

Very Important Paper
Department’s Most Read Paper on ResearchGate (August 2021)

DOI: 10.1002/anie.202108405

DOI (German version): 10.1002/ange.202108405

pt-frame2.jpg

[55] Angew. Chem. Int. Ed. 2021, 60, 16864–16868.

Platinum-Templated Coupling of B=N Units: Synthesis of BNBN Analogues of 1,3-Dienes and a Butatriene

C. Brunecker, M. Arrowsmith, F. Fantuzzi, H. Braunschweig*

DOI: 10.1002/anie.202106161

DOI (German version): 10.1002/ange.202106161

h2bpco.jpg

[54] Angew. Chem. Int. Ed. 2021, 60, 13666–13670.

Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry

S. Hagspiel, F. Fantuzzi, R. D. Dewhurst, A. Gärtner, F. Lindl, A. Lamprecht, H. Braunschweig*

DOI: 10.1002/anie.202103521

DOI (German version): 10.1002/ange.202103521

b2p2.jpg

[53] Angew. Chem. Int. Ed. 2021, 60, 13661–13665.

Isolation of Neutral, Mono-, and Dicationic B2P2 Rings by Diphosphorus Addition to a Boron–Boron Triple Bond

T. Brückner, F. Fantuzzi, T. E. Stennett, I. Krummenacher, R. D. Dewhurst, B. Engels, H. Braunschweig*

DOI: 10.1002/anie.202102218

DOI (German version): 10.1002/ange.202102218

bncs.jpg

[52] Angew. Chem. Int. Ed. 2021, 60, 6446–6450.

Highly Colored Boron-Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates

S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, A. Hermann, T. Brückner, H. Braunschweig*

DOI: 10.1002/anie.202015508

DOI (German Version): 10.1002/ange.202015508

beryllole.jpg

[51] Angew. Chem. Int. Ed. 2021, 60, 3812–3819.

Isolation and Reactivity of an Antiaromatic s-Block Metal Compound

D. K. Roy, T. Tröster, F. Fantuzzi, R. D. Dewhurst, C. Lenczyk, K. Radacki, C. Pranckevicius, B. Engels*, H. Braunschweig*

Highlighted in Chemistry World

DOI: 10.1002/anie.202014557

DOI (German version): 10.1002/ange.202014557

bco.jpg

[50] Angew. Chem. Int. Ed. 2021, 2963–2968.

Reduction and Rearrangement of a Boron(I) Carbonyl Complex

M. Rang, F. Fantuzzi, M. Arrowsmith, I. Krummenacher, E. Beck, R. Witte, A. Matler, A. Rempel, T. Bischof, K. Radacki, B. Engels, H. Braunschweig*

DOI: 10.1002/anie.202014167

DOI (German Version): 10.1002/ange.202014167

helical.jpg

[49] Chem. Sci. 2021, 12, 11864-11872.

One- and Two-Electron Reduction of Triarylborane-Based Helical Donor-Acceptor Compounds

X. Jia, J. Nitsch, Z. Wu, A. Friedrich, J. Krebs, I. Krumennacher, F. Fantuzzi, H. Braunschweig, M. Moos, C. Lambert, B. Engels, T. Marder*

DOI: 10.1039/D1SC02409D

cyano-isothio.jpg

[48] Chem. Sci. 2021, 12, 7937–7942.

Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity

S. Hagspiel, E. Dren, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, M. Härterich, I. Krummenacher,  H. Braunschweig*

DOI: 10.1039/D1SC01580J

alkynyl.jpg

[47] Chem. Commun. 2021, 57, 2645–2648.

Dialkynyldiboranes(4) and the selectable reactivity of their C–H, C≡C and B–B bonds

F. Schorr, F. Fantuzzi, R. D. Dewhurst, H. Braunschweig*

DOI: 10.1039/D1CC00265A

mn2.jpg

[46] Chem. Eur. J. 2021, 27, 12126–12136.

Taming the Antiferromagnetic Beast: Computational Design of Ultrashort Mn−Mn Bonds Stabilized by N-Heterocyclic Carbenes

M. A. S. Francisco,† F. Fantuzzi*, T. M. Cardozo, P. M. Esteves, B. Engels, R. R. Oliveira* (†: contributed equally)

DOI: 10.1002/chem.202101116

bridged.jpg

[45] Chem. Eur. J. 2021, 27, 5160–5170.

Twisting versus Delocalization in CAAC- and NHC-Stabilized Boron-Based Biradicals: The Roles of Sterics and Electronics

P. Schmid, F. Fantuzzi, J. Klopf, N. B. Schröder, R. D. Dewhurst, H. Braunschweig, V. Engel, B. Engels*

Hot Paper

Highlighted as Front Cover

Highlighted as Cover Profile

DOI: 10.1002/chem.202004619

metalatranes.jpg

[44] Inorg. Chem. 2021, 60, 17, 12790-12800.

Understanding, Modulating, and Leveraging Transannular M→Z Interactions

B. Ghosh, F. Fantuzzi, A. Phukan*

Department’s Most Read Paper on ResearchGate (August 2021)

DOI: 10.1021/acs.inorgchem.1c00977

nanowheel.jpg

[43] Dalton Trans. 2021, 50, 12430-12434.

Unexpected formation of a dodecanuclear {Co(II)6Cu(II)6} nanowheel under ambient conditions: magneto-structural correlations

W. D. do Pim, I. F. Silva, E. N. da Silva Jr., H. O. Stumpf, W. X. C. Oliveira, E. F. Pedroso, C. B. Pinheiro. Y. Journaux, F. Fantuzzi, I. Krummenacher, H. Braunschweig, B. Engels, J. Cano*, M. Julve, C. L. M. Pereira*

DOI: 10.1039/D1DT02268G

nb2.jpg

[42] Dalton Trans. 2021, 50, 840–849.

Splitting of Multiple Hydrogen Molecules by Bioinspired Diniobium Metal Complexes: A DFT Study

F. Fantuzzi, M. A. C. Nascimento*, B. Ginovska, R. M. Bullock, S. Raugei*

Highlighted as Front Cover

Highlighted in Dalton Transactions HOT Articles
DOI: 10.1039/D0DT03411H

rhodium.jpg

[41] J. Org. Chem. 2021, 86, 264–278.

Rhodium(III)-Catalyzed C–H/N–H Alkyne Annulation of Non-Symmetric 2-Aryl-(Benz)Imidazole Derivatives: Photophysical and Mechanistic Insights

G. Dias, E. Paz, J. Kadooka, A. Sabino, L. Cury, K. Torikai, C. Simone, F. Fantuzzi, E. N. da Silva Jr.*

DOI: 10.1021/acs.joc.0c02054

lif.jpg

[40] J. Appl. Phys. 2021, 129, 205102.

Ab initio study of structural and electronic properties of lithium fluoride nanotubes

R. R. Oliveira*, F. Fantuzzi*, M. A. C. Nascimento*

DOI: 10.1063/5.0047243

dba.jpg

[39] Angew. Chem. Int. Ed. 2020, 59, 19338–19343.

cAAC-Stabilized 9,10-diboraanthracenes – acenes with open-shell singlet biradical ground states

C. Saalfrank, F. Fantuzzi, T. Kupfer, B. Ritschel, A. Matler, K. Hammond, I. Krummenacher, R. Bertermann, R. Wirthensohn, M. Finze, P. Schmid, V. Engel, B. Engels, H. Braunschweig*

Very Important Paper

DOI: 10.1002/anie.202008206

DOI (German version): 10.1002/ange.202008206

vinyldib.jpg

[38] Angew. Chem. Int. Ed. 2020, 59, 15717–15725.

Oxidation, Coordination and Nickel-Mediated Deconstruction of a Highly Electron-Rich Diboron Analogue of 1,3,5-Hexatriene

A. Herrmann†, F. Fantuzzi†, M. Arrowsmith, T. Zorn, I. Krummenacher, B. Ritschel, K. Radacki, B. Engels, H. Braunschweig*  (†: contributed equally)

DOI: 10.1002/anie.202006131

DOI (German version): 10.1002/ange.202006131

azides.jpg

[37] Angew. Chem. Int. Ed. 2020, 59, 15480–15486.

Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes

T. Thiess, G. Bélanger-Chabot†, F. Fantuzzi, M. Michel, M. Ernst, B. Engels, H. Braunschweig* (†: contributted equally)

Department's Most Read Paper on ResearchGate (July 2020)

DOI: 10.1002/anie.202003050

DOI (German version): 10.1002/ange.202003050

rhazaborete.jpg

[36] Chem. Sci. 2020, 11, 9134–9140.

Diverse Ring-Opening Reactions of Rhodium η4-Azaborete Complexes

M. Heß, T. E. Stennett, F. Fantuzzi, R. Bertermann, M. Schock, M. Schäfer, T. Thiess, H. Braunschweig*

DOI: 10.1039/D0SC02283G

toc_stephan.gif

[35] Chem. Sci. 2020, 11, 551–555.

Reduction of a Dihydroboryl Cation to a Boryl Anion and its Air-Stable, Neutral Hydroboryl Radical through Hydrogen Shuttling

S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Hermann, V. Paprocki, R. Drescher, I. Krummenacher, H. Braunschweig*
 

DOI: 10.1039/C9SC05026D

boratafulv.jpg

[34] Chem. Commun. 2020, 56, 14809–14812.

Tuneable reduction of cymantrenylboranes to diborenes or borylene-derived boratafulvenes

U. Schmidt, F. Fantuzzi, M. Arrowsmith, A. Hermann, D. Prieschl, A. Rempel, B. Engels, H. Braunschweig*

DOI: 10.1039/D0CC06398C

wn2.jpg

[33] Chem. Eur. J. 2020, 26, 16019–16027.

Functionalization of N2 via Formal 1,3-Haloboration of a Tungsten(0) σ-Dinitrogen Complex

A. Rempel, S. K. Mellerup. F. Fantuzzi, A. Herzog, A. Deißenberger, R. Bertermann, B. Engels, H. Braunschweig*

DOI: 10.1002/chem.202002678

ruthenium.jpg

[32] Chem. Eur. J. 2020, 26, 10981–10986.

Ruthenium(II)-Catalyzed Double Annulation of Quinones: Step-Economical Access to Valuable Bioactive Compounds

E. N. da Silva Jr.*, R. L. Carvalho, R. G. Almeida, L. G. Rosa, F. Fantuzzi, T. Rogge, P. M. S. Costa, C. O. Pessoa, C. Jacob, L. Ackermann*

Highlighted in Hot Topic: C-H Activation

Special Issue: 8th EuChemS Chemistry Congress

DOI: 10.1002/chem.202001434

ptaframe.jpg

[31] Chem. Eur. J. 2020, 26, 8518–8523.

Boranediyl- and Diboran(4)-1,2-diyl-bridged Platinum A-Frame Complexes

C. Brunecker, J. H. Müssig, M. Arrowsmith, F. Fantuzzi, A. Stoy, J. Böhnke, A. Hofmann, R. Bertermann, B. Engels, H. Braunschweig*

Department's Most Read Paper on ResearchGate (March 2020)

DOI: 10.1002/chem.202001168

2019_Soren.jpg

[30] J. Am. Chem. Soc. 2019, 141, 1695416960.

Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions

S. Mellerup, Y. Cui, F. Fantuzzi, P. Schmid, J. Goettel, G. Bélanger-Chabot, M. Arrowsmith, I. Krummenacher, Q. Ye, V. Engel, B. Engels, H. Braunschweig*

DOI: 10.1021/jacs.9b09128

2019_conor.jpg

[29] Angew. Chem. Int. Ed. 2019, 58, 12893–12897.

Bond‐Strengthening Backdonation in Aminoborylene‐Stabilized Aminoborylenes: At the Intersection of Borylenes and Diborenes

C. Pranckevicius, C. Herok, F. Fantuzzi, B. Engels, H. Braunschweig*

Hot Paper

Special Issue: Science Forum 2019

DOI: 10.1002/anie.201906671

DOI (German version): 10.1002/ange.201906671

2019_valerie

[28] Chem. Commun. 2019, 55, 9677–9680.

Selective Mono- and Dimetallation of a Group 3 Sandwich Complex

A. J. Martínez-Martínez, A. R. Kennedy, V. Paprocki, F. Fantuzzi, R. D. Dewhurst, C. T. O'Hara, H. Braunschweig*, R. E. Mulvey*

DOI: 10.1039/C9CC03825F

2019_LiF.jpg

[27] Chem. Eur. J. 2019, 25, 5269–5279.

Mechanistic Insights into the Formation of Lithium Fluoride Nanotubes

F. Fantuzzi, R. R. Oliveira, A. Henkes, J. Rubayo-Soneira, M. A. C. Nascimento*

DOI: 10.1002/chem.201805991

2019_Dibnano.jpg

[26] Inorg. Chem. 2018,  57, 3931–3940.

Diboryne Nanostructures Stabilized by Multitopic N-Heterocyclic Carbenes: A Computational Study

F. Fantuzzi, C. B. Coutinho, R. R. Oliveira, M. A. C. Nascimento*

DOI: 10.1021/acs.inorgchem.8b00089

78779489-2.jpg

[25] Chem. Eur. J. 2015, 21, 7814–7819.

Prediction of Boron-Boron Triple-Bond Polymers Stabilized by Janus-Type bis(N-Heterocyclic) Carbenes

F. Fantuzzi, M. A. C. Nascimento*

DOI: 10.1002/chem.201500241

78779489-2.jpg

[24] Synlett 2014, 25, 1043–1044.

Mercury(II) Chloride

F. Fantuzzi*

DOI: 10.1055/s-0033-1340958