Tubos de ensaio
Main-group and
Organometallic chemistry

[60] Angew. Chem. Int. Ed. 2021, Accepted.


S. Nees†, F. Fantuzzi†, T. Wellnitz, M. Fischer, J.-E. Siewert, J. T. Goettel, A. Hofmann, M. Härterich, H. Braunschweig*, C. Hering-Junghans* 
(†: contributed equally) 

DOI: 10.1002/anie.202111121

DOI (German Version): 10.1002/ange.202111121


[59] Angew. Chem. Int. Ed. 2021, Accepted.

The Dimethylbismuth Cation: Entry into Dative Bi–Bi Bonding and Unconventional Methyl Exchange

J. Ramler, F. Fantuzzi, F. Geist, A. Hanft, H. Braunschweig, B. Engels, C. Lichtenberg*

Hot Paper

DOI: 10.1002/anie.202109545

DOI (German Version): 10.1002/ange.202109545


[58] Chem. Eur. J. 2021, Accepted.

Controlled Synthesis of Oligomers Containing Main-Chain B(sp2)-B(sp2) Bonds

F. Schorr, N. Schopper, N. Riensch, F. Fantuzzi, M. Neder, R. Dewhurst, T. Thiess, T. Brückner, K. Hammond, H. Helten, M. Finze, H. Braunschweig*

DOI: 10.1002/chem.202102721


[57] Chem. Eur. J. 2021, Accepted.

Diphosphino-Functionalized 1,8-Naphthyridines: a Multifaceted Ligand Platform for Boranes and Diboranes

J. Cui, M. Dietz, M. Härterich, F. Fantuzzi, W. Lu, R. Dewhurst, H. Braunschweig*

DOI: 10.1002/chem.202102721


[56] Angew. Chem. Int. Ed. 2021, 60, 20776-20780.

A Neutral Beryllium(I) Radical

C. Czernetzki, M. Arrowsmith, F. Fantuzzi, A. Gärtner, I. Krummenacher, F. Schorr, T. Tröster, H. Braunschweig*

Very Important Paper
Department’s Most Read Paper on ResearchGate (August 2021)

DOI: 10.1002/anie.202108405

DOI (German version): 10.1002/ange.202108405


[55] Angew. Chem. Int. Ed. 2021, 60, 16864–16868.

Platinum-Templated Coupling of B=N Units: Synthesis of BNBN Analogues of 1,3-Dienes and a Butatriene

C. Brunecker, M. Arrowsmith, F. Fantuzzi, H. Braunschweig*

DOI: 10.1002/anie.202106161

DOI (German version): 10.1002/ange.202106161


[54] Angew. Chem. Int. Ed. 2021, 60, 13666–13670.

Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry

S. Hagspiel, F. Fantuzzi, R. D. Dewhurst, A. Gärtner, F. Lindl, A. Lamprecht, H. Braunschweig*

DOI: 10.1002/anie.202103521

DOI (German version): 10.1002/ange.202103521


[53] Angew. Chem. Int. Ed. 2021, 60, 13661–13665.

Isolation of Neutral, Mono-, and Dicationic B2P2 Rings by Diphosphorus Addition to a Boron–Boron Triple Bond

T. Brückner, F. Fantuzzi, T. E. Stennett, I. Krummenacher, R. D. Dewhurst, B. Engels, H. Braunschweig*

DOI: 10.1002/anie.202102218

DOI (German version): 10.1002/ange.202102218


[52] Angew. Chem. Int. Ed. 2021, 60, 6446–6450.

Highly Colored Boron-Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates

S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, A. Hermann, T. Brückner, H. Braunschweig*

DOI: 10.1002/anie.202015508

DOI (German Version): 10.1002/ange.202015508


[51] Angew. Chem. Int. Ed. 2021, 60, 3812–3819.

Isolation and Reactivity of an Antiaromatic s-Block Metal Compound

D. K. Roy, T. Tröster, F. Fantuzzi, R. D. Dewhurst, C. Lenczyk, K. Radacki, C. Pranckevicius, B. Engels*, H. Braunschweig*

Highlighted in Chemistry World

DOI: 10.1002/anie.202014557

DOI (German version): 10.1002/ange.202014557


[50] Angew. Chem. Int. Ed. 2021, 2963–2968.

Reduction and Rearrangement of a Boron(I) Carbonyl Complex

M. Rang, F. Fantuzzi, M. Arrowsmith, I. Krummenacher, E. Beck, R. Witte, A. Matler, A. Rempel, T. Bischof, K. Radacki, B. Engels, H. Braunschweig*

DOI: 10.1002/anie.202014167

DOI (German Version): 10.1002/ange.202014167


[49] Chem. Sci. 2021, 12, 11864-11872.

One- and Two-Electron Reduction of Triarylborane-Based Helical Donor-Acceptor Compounds

X. Jia, J. Nitsch, Z. Wu, A. Friedrich, J. Krebs, I. Krumennacher, F. Fantuzzi, H. Braunschweig, M. Moos, C. Lambert, B. Engels, T. Marder*

DOI: 10.1039/D1SC02409D


[48] Chem. Sci. 2021, 12, 7937–7942.

Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity

S. Hagspiel, E. Dren, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, M. Härterich, I. Krummenacher,  H. Braunschweig*

DOI: 10.1039/D1SC01580J


[47] Chem. Commun. 2021, 57, 2645–2648.

Dialkynyldiboranes(4) and the selectable reactivity of their C–H, C≡C and B–B bonds

F. Schorr, F. Fantuzzi, R. D. Dewhurst, H. Braunschweig*

DOI: 10.1039/D1CC00265A


[46] Chem. Eur. J. 2021, 27, 12126–12136.

Taming the Antiferromagnetic Beast: Computational Design of Ultrashort Mn−Mn Bonds Stabilized by N-Heterocyclic Carbenes

M. A. S. Francisco,† F. Fantuzzi*, T. M. Cardozo, P. M. Esteves, B. Engels, R. R. Oliveira* (†: contributed equally)

DOI: 10.1002/chem.202101116


[45] Chem. Eur. J. 2021, 27, 5160–5170.

Twisting versus Delocalization in CAAC- and NHC-Stabilized Boron-Based Biradicals: The Roles of Sterics and Electronics

P. Schmid, F. Fantuzzi, J. Klopf, N. B. Schröder, R. D. Dewhurst, H. Braunschweig, V. Engel, B. Engels*

Hot Paper

Highlighted as Front Cover

Highlighted as Cover Profile

DOI: 10.1002/chem.202004619


[44] Inorg. Chem. 2021, 60, 17, 12790-12800.

Understanding, Modulating, and Leveraging Transannular M→Z Interactions

B. Ghosh, F. Fantuzzi, A. Phukan*

Department’s Most Read Paper on ResearchGate (August 2021)

DOI: 10.1021/acs.inorgchem.1c00977


[43] Dalton Trans. 2021, 50, 12430-12434.

Unexpected formation of a dodecanuclear {Co(II)6Cu(II)6} nanowheel under ambient conditions: magneto-structural correlations

W. D. do Pim, I. F. Silva, E. N. da Silva Jr., H. O. Stumpf, W. X. C. Oliveira, E. F. Pedroso, C. B. Pinheiro. Y. Journaux, F. Fantuzzi, I. Krummenacher, H. Braunschweig, B. Engels, J. Cano*, M. Julve, C. L. M. Pereira*

DOI: 10.1039/D1DT02268G


[42] Dalton Trans. 2021, 50, 840–849.

Splitting of Multiple Hydrogen Molecules by Bioinspired Diniobium Metal Complexes: A DFT Study

F. Fantuzzi, M. A. C. Nascimento*, B. Ginovska, R. M. Bullock, S. Raugei*

Highlighted as Front Cover

Highlighted in Dalton Transactions HOT Articles
DOI: 10.1039/D0DT03411H


[41] J. Org. Chem. 2021, 86, 264–278.

Rhodium(III)-Catalyzed C–H/N–H Alkyne Annulation of Non-Symmetric 2-Aryl-(Benz)Imidazole Derivatives: Photophysical and Mechanistic Insights

G. Dias, E. Paz, J. Kadooka, A. Sabino, L. Cury, K. Torikai, C. Simone, F. Fantuzzi, E. N. da Silva Jr.*

DOI: 10.1021/acs.joc.0c02054


[40] J. Appl. Phys. 2021, 129, 205102.

Ab initio study of structural and electronic properties of lithium fluoride nanotubes

R. R. Oliveira*, F. Fantuzzi*, M. A. C. Nascimento*

DOI: 10.1063/5.0047243


[39] Angew. Chem. Int. Ed. 2020, 59, 19338–19343.

cAAC-Stabilized 9,10-diboraanthracenes – acenes with open-shell singlet biradical ground states

C. Saalfrank, F. Fantuzzi, T. Kupfer, B. Ritschel, A. Matler, K. Hammond, I. Krummenacher, R. Bertermann, R. Wirthensohn, M. Finze, P. Schmid, V. Engel, B. Engels, H. Braunschweig*

Very Important Paper

DOI: 10.1002/anie.202008206

DOI (German version): 10.1002/ange.202008206


[38] Angew. Chem. Int. Ed. 2020, 59, 15717–15725.

Oxidation, Coordination and Nickel-Mediated Deconstruction of a Highly Electron-Rich Diboron Analogue of 1,3,5-Hexatriene

A. Herrmann†, F. Fantuzzi†, M. Arrowsmith, T. Zorn, I. Krummenacher, B. Ritschel, K. Radacki, B. Engels, H. Braunschweig*  (†: contributed equally)

DOI: 10.1002/anie.202006131

DOI (German version): 10.1002/ange.202006131


[37] Angew. Chem. Int. Ed. 2020, 59, 15480–15486.

Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes

T. Thiess, G. Bélanger-Chabot†, F. Fantuzzi, M. Michel, M. Ernst, B. Engels, H. Braunschweig* (†: contributted equally)

Department's Most Read Paper on ResearchGate (July 2020)

DOI: 10.1002/anie.202003050

DOI (German version): 10.1002/ange.202003050


[36] Chem. Sci. 2020, 11, 9134–9140.

Diverse Ring-Opening Reactions of Rhodium η4-Azaborete Complexes

M. Heß, T. E. Stennett, F. Fantuzzi, R. Bertermann, M. Schock, M. Schäfer, T. Thiess, H. Braunschweig*

DOI: 10.1039/D0SC02283G


[35] Chem. Sci. 2020, 11, 551–555.

Reduction of a Dihydroboryl Cation to a Boryl Anion and its Air-Stable, Neutral Hydroboryl Radical through Hydrogen Shuttling

S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Hermann, V. Paprocki, R. Drescher, I. Krummenacher, H. Braunschweig*

DOI: 10.1039/C9SC05026D


[34] Chem. Commun. 2020, 56, 14809–14812.

Tuneable reduction of cymantrenylboranes to diborenes or borylene-derived boratafulvenes

U. Schmidt, F. Fantuzzi, M. Arrowsmith, A. Hermann, D. Prieschl, A. Rempel, B. Engels, H. Braunschweig*

DOI: 10.1039/D0CC06398C


[33] Chem. Eur. J. 2020, 26, 16019–16027.

Functionalization of N2 via Formal 1,3-Haloboration of a Tungsten(0) σ-Dinitrogen Complex

A. Rempel, S. K. Mellerup. F. Fantuzzi, A. Herzog, A. Deißenberger, R. Bertermann, B. Engels, H. Braunschweig*

DOI: 10.1002/chem.202002678


[32] Chem. Eur. J. 2020, 26, 10981–10986.

Ruthenium(II)-Catalyzed Double Annulation of Quinones: Step-Economical Access to Valuable Bioactive Compounds

E. N. da Silva Jr.*, R. L. Carvalho, R. G. Almeida, L. G. Rosa, F. Fantuzzi, T. Rogge, P. M. S. Costa, C. O. Pessoa, C. Jacob, L. Ackermann*

Highlighted in Hot Topic: C-H Activation

Special Issue: 8th EuChemS Chemistry Congress

DOI: 10.1002/chem.202001434


[31] Chem. Eur. J. 2020, 26, 8518–8523.

Boranediyl- and Diboran(4)-1,2-diyl-bridged Platinum A-Frame Complexes

C. Brunecker, J. H. Müssig, M. Arrowsmith, F. Fantuzzi, A. Stoy, J. Böhnke, A. Hofmann, R. Bertermann, B. Engels, H. Braunschweig*

Department's Most Read Paper on ResearchGate (March 2020)

DOI: 10.1002/chem.202001168


[30] J. Am. Chem. Soc. 2019, 141, 1695416960.

Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions

S. Mellerup, Y. Cui, F. Fantuzzi, P. Schmid, J. Goettel, G. Bélanger-Chabot, M. Arrowsmith, I. Krummenacher, Q. Ye, V. Engel, B. Engels, H. Braunschweig*

DOI: 10.1021/jacs.9b09128


[29] Angew. Chem. Int. Ed. 2019, 58, 12893–12897.

Bond‐Strengthening Backdonation in Aminoborylene‐Stabilized Aminoborylenes: At the Intersection of Borylenes and Diborenes

C. Pranckevicius, C. Herok, F. Fantuzzi, B. Engels, H. Braunschweig*

Hot Paper

Special Issue: Science Forum 2019

DOI: 10.1002/anie.201906671

DOI (German version): 10.1002/ange.201906671


[28] Chem. Commun. 2019, 55, 9677–9680.

Selective Mono- and Dimetallation of a Group 3 Sandwich Complex

A. J. Martínez-Martínez, A. R. Kennedy, V. Paprocki, F. Fantuzzi, R. D. Dewhurst, C. T. O'Hara, H. Braunschweig*, R. E. Mulvey*

DOI: 10.1039/C9CC03825F


[27] Chem. Eur. J. 2019, 25, 5269–5279.

Mechanistic Insights into the Formation of Lithium Fluoride Nanotubes

F. Fantuzzi, R. R. Oliveira, A. Henkes, J. Rubayo-Soneira, M. A. C. Nascimento*

DOI: 10.1002/chem.201805991


[26] Inorg. Chem. 2018,  57, 3931–3940.

Diboryne Nanostructures Stabilized by Multitopic N-Heterocyclic Carbenes: A Computational Study

F. Fantuzzi, C. B. Coutinho, R. R. Oliveira, M. A. C. Nascimento*

DOI: 10.1021/acs.inorgchem.8b00089


[25] Chem. Eur. J. 2015, 21, 7814–7819.

Prediction of Boron-Boron Triple-Bond Polymers Stabilized by Janus-Type bis(N-Heterocyclic) Carbenes

F. Fantuzzi, M. A. C. Nascimento*

DOI: 10.1002/chem.201500241


[24] Synlett 2014, 25, 1043–1044.

Mercury(II) Chloride

F. Fantuzzi*

DOI: 10.1055/s-0033-1340958